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All issues Volume 5 (2014) EPJ Photovolt., 5 (2014) 50601 Full HTML
Open Access
Issue
EPJ Photovolt.
Volume 5, 2014
Article Number 50601
Number of page(s) 5
Section Optics of Thin Films, TCOs
DOI https://doi.org/10.1051/epjpv/2014006
Published online 16 July 2014

© Boccard et al., published by EDP Sciences, 2014

Licence Creative CommonsThis is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

1 Introduction

Minimizing the absorption of non-photoactive layers is of crucial importance for most solar cell technologies. When a direct-band-gap photoactive material (such as gallium-arsenide) is used, parasitic absorption impinges on the photon recycling process and reduces the achievable voltage output [1]; whereas when indirect-band-gap photoactive material (such as silicon) is used, this parasitic absorption impinges on the current density output [2, 3, 4, 5]. In the case of thin-film silicon technology, parasitic absorption due to non-active layer has been identified as a major limitation for present devices [6, 7].

We focus in the following on micromorph tandem cells, which consist of a hydrogenated amorphous silicon (a-Si:H) top cell and a hydrogenated microcrystalline silicon (μc-Si:H) bottom cell. For this device, light trapping strategies are applied for a broad wavelength range of the solar spectrum, covering the near infrared (NIR) range between 600 nm and 1100 nm. The absorption coefficient of μc-Si:H silicon being weak in the NIR, efficient light trapping (typically via nanotextured interfaces) is mandatory to achieve large currents [7, 8, 9, 10, 11, 12, 13, 14]. Yet, in the presence of a very efficient light-trapping scheme, parasitic absorption (AP) due to the non-photoactive layers (such as the doped layers, the electrodes and the back reflector) is also increased compared to a flat cell configuration [6, 15, 16, 17]. For transparent conductive oxide (TCO) based front electrodes, decreasing the free-carrier density enables to greatly increase the transparency in the NIR [17, 18, 19].

In this work, we separate the influence of parasitic absorption in the front and back electrodes by using ZnO in both cases. Two different doping levels are compared for both electrodes, leading to four possible combinations of front and back electrodes. The sheet resistance is kept identical in all cases, and the light-scattering properties of all front electrodes are identical as well. Both electrodes are shown to have similar influence in the NIR spectrum range, which is confirmed by simulations.

2 Experimental details

The devices studied here are micromorph cells deposited by plasma enhanced chemical vapor deposition (PECVD). An in-situ 70-nm-thick silicon-oxide based intermediate reflecting layer (SiO-based IRL) [20, 21] is inserted between the 240-nm-thick a-Si:H top cell and the 2.8-μm-thick μc-Si:H bottom cell. Front and back electrodes are made of ZnO deposited by low pressure chemical vapor deposition (LPCVD).

Figure 1 schematically presents the four micromorph devices compared here. Their front and back electrodes are the only changing parameters and two options are used: thick, non-intentionally-doped (n-i-d) LPCVD ZnO or thin, doped LPCVD ZnO. The free-carrier density in the n-i-d ZnO is around 1.2 × 1019cm-3 and it is 1.0 × 1020cm-3 in the doped one. The sheet resistance is kept similar for all electrodes (between 7 Ω /□ and 12 Ω /□) thanks to the much larger thickness in the n-i-d case. In order to keep the same morphology for both types of front electrodes, a stack of two layers is used in the n-i-d case. A 7-μm-thick layer is first deposited on glass and flattened by chemo-mechanical polishing (CMP) to erase the very large pyramidal features that naturally form on its surface during layer growth [22]. This polishing is made by immersing the sample in a diluted suspension of silica nanoparticles as typically used for CMP, and scanning the surface with a felt-covered drill-head. To inhibit epitaxial growth on this polished surface, an ultra-thin (< 3 nm) n-doped μc-Si:H layer is subsequently deposited; a n-i-d ZnO film is then deposited on top, with thickness adjusted to match the surface morphology of the 2-μm-thick doped layer. Due to a reduction of the lateral growth rate of the grains when LPCVD ZnO is doped [22], this rough n-i-d layer is only 1.6-μm-thick.

thumbnail Fig. 1

Schematic view of the stacks composing the A, B, C and D micromorph devices. Only the front and back electrodes are changed. Light enters the devices from the top.

For the back electrode, both electrodes are single-layers, 7-μm-thick for the n-i-d case and 2-μm-thick for the doped one. Though these back electrodes exhibit therefore different surface roughnesses, this was shown to have no noticeable impact on the light-trapping behavior of such devices, due to the efficient light scattering provided by the front electrode [23].

3 Results and discussion

Figure 2a compares absorptance measurements of the 8-μm-thick n-i-d ZnO stack and the 2-μm-thick doped ZnO layer. For wavelengths up to 550 nm the doped layer absorbs less than the n-i-d stack. This is due first to the Burstein-Moss effect, widening the band-gap in the case of the doped ZnO [24], but also to enhanced sub-gap absorption in the n-i-d stack because of the larger thickness. However, above 550 nm, the higher free-carrier absorption (FCA) in the doped single layer makes the n-i-d stack more transparent despite its larger thickness.

thumbnail Fig. 2

(a) Absorptance of ZnO front electrodes used in this study as sketched in Figure 1, and of the optimized electrode used in the device of Figure 4. These measurements were made in air with an index-matching liquid (CH2I2). (b) EQE and 1-Reflection (1-R) of the four micromorph devices sketched in Figure 1 having only their ZnO electrodes changed. The number in parenthesis are current density values for the top and bottom cells, in mA/cm2.

Figure 2b shows the external quantum efficiency (EQE) spectrum of top and bottom cells for the four possible micromorph configurations employing these electrodes in front and back. The similarity of the morphology of all front electrodes is assessed by the perfect matching of the crossing of the top and bottom EQE curves for all substrates at the same wavelength (650 nm) [25]. The top cell current is only affected for such a thick cell by the front electrode (A, B and C, D are superimposed), and the higher optical band gap of the thin doped TCO layer enables a 0.2 mA cm-2current gain. Then, the bottom cell is sensitive to the transparency of both electrodes, and in a very similar way, as deduced from the striking superimposition of the B and C curves and the identical current densities. This can also be seen in Figure 3a, which indicates the relative parasitic absorption for all cases compared to case A, evidencing the identical effect of FCA in the back or front electrode.

However, the current gained in the bottom cell by improving the transparency of the back electrode (i.e. going from B to A or from D to C) depends on the front electrode properties: 0.7 mA cm-2are gained between B and A, whereas only 0.5 mA cm-2is gained between D and C. This is illustrated with curves of relative spectral current density gain in Figure 3b. The same applies when improving the transparency of the front electrode: 0.7 mA cm-2are gained in the bottom cell for C to A, but only 0.5 mA cm-2for D to B. The current gain when making one electrode more transparent therefore scales with the transparency of the other electrode, a more transparent unchanged electrode leading to a larger gain.

This difference comes from the fact that the light saved from parasitic absorption in one of the electrodes (by making it more transparent) will be distributed between valuable absorption (EQE), escape from the cell (R) and parasitic absorption in the remaining parasitically absorbing layers (AP). The probability of the latter increases with the parasitic absorption of the unchanged electrode, as will be seen with modeling in the next section. This indicates that the largest gains from parasitic absorption reduction are expected when improving already well transparent electrodes. However, as evidenced by Battaglia et al. [2], doped layers also contribute to parasitic absorption. Their contribution to parasitic absorption might therefore at some point become larger than the contribution of the electrode, making further improving the electrode transparency of little effect.

thumbnail Fig. 3

(a) Relative parasitic absorption in the four micromorph devices sketched in Figure 1 compared to case A where both electrodes are non-intentionally-doped doped, and thus very transparent. (b) Spectral current density gain between configurations B and A, or D and C. In both cases, the same modification is made at the back electrode.

By combining high-quality silicon layers and highly transparent electrodes, a micromorph cell with 11.75% efficiency is obtained, as shown in Figure 4. The front and back electrodes are 2.3-μm-thick LPCVD ZnO layers with a low doping (carrier density of 2 × 1019) and a high mobility (over 50 cm2/V/s), resulting in a sheet resistance below 30 Ω /□ for a high transparency as seen in Figure 2a [25]. The thickness of the intrinsic layer of the a-Si:H top cell is 230 nm, and the thickness of the intrinsic layer of the μc-Si:H bottom cell is 2.3 μm. An 80-nm-thick SiO-based IRL with a refractive index of 1.9 is used between the top and bottom cells, an intrinsic SiO buffer layer was used in the a-Si:H cell and a p-type SiO layer was used in the μc-Si:H cell [20, 26]. The a-Si:H cell and the SiO-based IRL were made in an Octopus I cluster tool made by INDEOtec SA, whereas the μc-Si:H cell was made in a research-scale reactor developed in-house [27].

thumbnail Fig. 4

IV curve of a micromorph cell with an efficiency of 11.75%, deposited using highly transparent ZnO electrodes.

thumbnail Fig. 5

Simulated (solid) and measured (dashed) EQE, total absorptance (1 − R) and front, back and total AP curves simulated from experimental absorption data for the micromorph devices presented in Figure 1.

4 Modeling

Figure 5 shows various spectra obtained when simulating this set of experimental data with the model presented in reference [7]. Only a μc-Si:H cell is used for the model, and the resulting simulated EQE curve is compared to the curve obtained by summing the top- and bottom-cell EQE curves. In absence of a correct AFM scan of the front-electrode surface, the light-trapping parameters of the model (a0, b1 and R0) are fitted once for all four cases in absence of parasitic absorption using a “corrected EQE” (EQEc) curve, calculated from experimental EQE and R curves of one of the devices [16]. Then, the measured absorptance spectra of the two different types of layers are implemented in Afront and Aback, and the p-layer thickness is kept identical for all curves.

An excellent agreement between experimental and simulated EQE and R curves is obtained in the infrared part of the spectrum. A notable discrepancy of the simulation compared to the measurement is observed, similarly for all devices, in the 600 nm–900 nm wavelength range. This is attributed to the many additional layers present in the real micromorph device compared to the simplified model considering only a μc-Si:H cell, such as the intermediate reflector and a-Si:H doped layers. These layers induce extra parasitic absorption and reflection, that is not taken into account in the model.

The parasitic absorption curve experimentally deduced from AP = 1 − EQE − R is also plotted, as well as the curves representing calculated parasitic absorption which is attributed to the front side of the device (APfront), to the back side (APback), and the total parasitic absorption (APtot). It should be noted that possible collection issues are assimilated to AP in the measurements, whereas a 98% collection efficiency was set for the whole spectrum in the model for all four cases – explaining the 2%higher AP in all cases for the experimental case compared to the modeled case. As suggested by experimental measurements, APfront (resp. APback) is also influenced by the transparency of the layers at the back (resp. front) of the device: APfront is different between cases A and B, even though all layers at the front of the cell are unchanged. Also, for wavelengths larger than 700 nm, very similar APfront and APback are observed in symmetrical devices (A and D), which is in agreement with experimental findings.

5 Conclusion

We showed in this work that parasitic absorption in both electrodes of a solar cell has similar effect in the infra-red part of the spectrum. We assessed this result with simulations which reproduce well the observed trends. We also emphasized that a reduction of parasitic absorption in one electrode yields a larger EQE gain when the other electrode is made more transparent. Reducing the doping of TCO layers and compensating by thickness increase is shown to be an efficient way of reducing parasitic absorption in these layers. By using very transparent TCO layers and high-quality silicon layers, a micromorph device with 11.75% stable efficiency, independently certified by Fraunhofer ISE was obtained.

Acknowledgments

We thank the Swiss Federal Office for Energy for funding under grant SI/500750-01. A part of this work was carried out in the framework of the FP7 project “Fast Track”, funded by the EC under Grant agreement No. 283501.

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Cite this article as: Mathieu Boccard, Peter Cuony, Simon Hänni, Michael Stuckelberger, Franz-Josef Haug, Fanny Meillaud, Matthieu Despeisse, Christophe Ballif, The role of front and back electrodes in parasitic absorption in thin-film solar cells, EPJ Photovoltaics 5, 50601 (2014).

All Figures

thumbnail Fig. 1

Schematic view of the stacks composing the A, B, C and D micromorph devices. Only the front and back electrodes are changed. Light enters the devices from the top.
In the text
thumbnail Fig. 2

(a) Absorptance of ZnO front electrodes used in this study as sketched in Figure 1, and of the optimized electrode used in the device of Figure 4. These measurements were made in air with an index-matching liquid (CH2I2). (b) EQE and 1-Reflection (1-R) of the four micromorph devices sketched in Figure 1 having only their ZnO electrodes changed. The number in parenthesis are current density values for the top and bottom cells, in mA/cm2.
In the text
thumbnail Fig. 3

(a) Relative parasitic absorption in the four micromorph devices sketched in Figure 1 compared to case A where both electrodes are non-intentionally-doped doped, and thus very transparent. (b) Spectral current density gain between configurations B and A, or D and C. In both cases, the same modification is made at the back electrode.
In the text
thumbnail Fig. 4

IV curve of a micromorph cell with an efficiency of 11.75%, deposited using highly transparent ZnO electrodes.
In the text
thumbnail Fig. 5

Simulated (solid) and measured (dashed) EQE, total absorptance (1 − R) and front, back and total AP curves simulated from experimental absorption data for the micromorph devices presented in Figure 1.
In the text

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