Fig. 1

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The two-level model in the permanent (left panel) and transitory (right panel) regime of illumination. (Left panel) A molecular photocell with one HOMO and one LUMO orbitals attached to the electrodes. The red line represents the electron-hole interaction and recombination inside the molecule and the hopping integrals of electron and hole are denoted by C and J. E is the energy of absorbed photon. (Right panel) Schematic representation of a donor-acceptor system. Charge evacuation leads are considered as semi-infinite chains. Here, Je and Jh are the coupling energies between two adjacent sites in the electron and hole chains, respectively. Also, Ce and Ch represent the first coupling energies between the interface states and charge evacuation leads.
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