Table 6
Sensitivity of the pm-Si:H solar cell output to the ZnO:Al/P-μc-SiOx:H surface band bending. The case where the sbb = 0.2 eV (that is generally observed for ZnO:Al/P-a-SiC:H), is given in the first row of this table and assumed for the single window designs in Table 4. The front contact barrier height (ϕb0) for this case is 1.83 eV, since the band gap of P-μc-SiOx is taken to be 2.5 eV and its activation energy = 0.47 eV. Even for a slight increase of sbb – to 0.3 eV (ϕb0 = 1.73 eV), Voc, FF and the cell efficiency deteriorate appreciably (second line of table), as the Vbi falls. Any effort to increase the Vbi by increasing the P-μc-SiOx:H thickness, brings down the Jsc. The third line indicates the effect of having ϕb0 = 1.32 eV, the same as at the ZnO:Al/P-μc-Si:H interface of the double window design.
Cell type | Jsc (mA cm-2) | Voc (volts) | FF | Efficiency (%) | |
|
|||||
pm-Si:H, ZnO:Al/P-μc-SiOx:H | Initial | 15.89 | 1.124 | 0.760 | 13.56 |
sbb = 0.2 eV, ϕb0 = 1.83 eV | |||||
|
|||||
pm-Si:H, ZnO:Al/P-μc-SiOx:H | Initial | 15.88 | 1.039 | 0.732 | 12.07 |
sbb = 0.3 eV, ϕb0 = 1.73 eV | |||||
|
|||||
pm-Si:H, ZnO:Al/P-μc-SiOx:H | Initial | 15.81 | 0.629 | 0.614 | 6.11 |
sbb = 0.71 eV ϕb0 = 1.32 eV |
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